EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, acidity and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). ITS-90 water temperature and Water body salinity variables have been also included (as-is) to complete the Eutrophication and Acidity data. If you use these variables for calculations, please refer to SeaDataNet for having the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets . This aggregated dataset contains all unrestricted EMODnet Chemistry data on Eutrophication and Acidity (15 parameters with quality flag indicators), and covers the Mediterranean Sea with 187722 CDI records (180932 Vertical profiles and 6790 Time series). Vertical profiles temporal range is from 1911-08-17 to 2020-10-16. Time series temporal range is from 1974-06-04 to 2018-02-20. Data were aggregated and quality controlled by 'Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)' from Greece. Regional datasets concerning eutrophication and acidity are automatically harvested and resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all Sea Regions ( https://doi.org/10.6092/9f75ad8a-ca32-4a72-bf69-167119b2cc12). When not present in original data, Water body nitrate plus nitrite was calculated by summing up the Nitrates and Nitrites. Same procedure was applied for Water body dissolved inorganic nitrogen (DIN) which was calculated by summing up the Nitrates, Nitrites and Ammonium. Parameter names are based on P35, EMODnet Chemistry aggregated parameter names vocabulary, which is available at: https://www.bodc.ac.uk/resources/vocabularies/vocabulary_search/P35/. Detailed documentation is available at: https://dx.doi.org/10.6092/4e85717a-a2c9-454d-ba0d-30b89f742713 Explore and extract data at: https://emodnet-chemistry.webodv.awi.de/eutrophication%3EMediterranean The aggregated dataset can also be downloaded as ODV collection and spreadsheet, which is composed of metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The original datasets can be searched and downloaded from EMODnet Chemistry Chemistry CDI Data and Discovery Access Service: https://emodnet-chemistry.maris.nl/search

Water body dissolved inorganic nitrogen (DIN) - Seasonal Climatology for Gulf of Riga for the period 1994-2019 on the domain: Lon 22.3-25.0°E, Lat 56.8-58.4°N. Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7, using GEBCO 30sec topography for the spatial connectivity of water masses. Horizontal correlation length of 25 km and vertical correlation length of 10 m. Depth range: 0.0, 2.5, 5, 10, 15, 20, 25, 30, 40, 50 m. Units: µmol/l. The horizontal resolution of the produced DIVAnd maps grids is 0.01 degrees.

Moving 6-year analysis of Water body dissolved inorganic nitrogen (DIN) in the Baltic Sea. Four seasons (March-May, June-August, September-November, December-February). Every year of the time dimension corresponds to a 6-year centred average. Periods span between 1980-1985 and 2013-2018. Analyses for depths (m) (HELCOM standard depths): 0, 5, 10, 15, 20, 30, 40, 50, 60, 70, 80, 90, 100, 125, 150, 175, 200, 225, 250, 275, 300. Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. GEBCO Grid (30 arc-seconds) topography is used for the contouring preparation. Files contain analysed fields, error fields and combined field with the deepest value for each grid point selected. Also pre-masked fields using relative error threshold 0.3 and 0.5 are included. In the analyses the Correlation length in the horizontal direction were fixed to 80 km and in the vertical direction to 25 m. Signal to noise ratio were fixed to 1.0. Background fields were created using data for the given time period and season. Log transformation was used in the analyses. No detrending, advection constraints or weighting are applied. Unit is umol/l.

Water body dissolved inorganic nitrogen (DIN) - - Seasonal Climatology for Danube Delta (NW Black Sea) for the period 1980-2018 on the domain: Lon E28.5-30.5°E, Lat N43.7-45.6°N. (winter: December-February, - spring: March-May, - summer: June-August, - autumn: September-November). Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.5, using GEBCO 30sec topography for the spatial connectivity of water masses. Horizontal correlation length of 47.730km and vertical correlation length of 45m were applied. Depth range: 0, 2.0, 4.0, 6.0, 8.0, 10.0, 15.0, 20.0, 25.0, 30.0, 40.0, 50.0. Units: umol/l. The horizontal resolution of the produced DIVAnd maps grids is 0.01 degrees.

Moving 6-year analysis and visualization of Water body dissolved inorganic nitrogen (DIN) in the North Sea, four seasons: winter (dec-feb), spring (mar-may), summer (jun-aug), autumn (sep-nov). Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVAnd (Data-Interpolating Variational Analysis) tool, version 2.7.2. results were subjected to the minfield option in DIVAnd to avoid negative/underestimated values in the interpolated results; error threshold masks L1 (0.3) and L2 (0.5) are included as well as the unmasked field. The depth dimension allows visualizing the gridded field at various depths.

Dissolved inorganic nitrogen (DIN) - Seasonal Climatology for Po River for the period 1980-2019 on the domain: Lon E12.0-14.0 deg.E, Lat N44.0-46.00 deg.N. Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. A relative correlation length used based on topography gradients and the horizontal correlation length varies from 25 km to 12.5 km. The vertical correlation length (in meters) is: [4.,4.,4.,4.,4.,10.,10.,10.,10.,20.,20.,20.,20.,20.]. Depth range: [0., 2., 4., 6., 8., 10., 15., 20., 25., 30., 40., 50., 60., 70.]. Units: umol/l. The horizontal resolution of the produced DIVAnd maps grids is dx=dy=0.009 degrees (around 975m and 708m accordingly). Additional analysis parameters: The error variance (epsilon2) was set equal to 1. Data weight was reduced near the coasts. Data weighting was applied with the following threshold values: lon=0.03, lat=0.03, depth=2. Threshold value for log transformation=200. Seasons definition: Winter=Jan-Mar, Spring=Apr-Jun, Summer=Jul-Sep, Autumn=Oct-Dec. DOI: 10.6092/p8ec-3v81

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, acidity and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). ITS-90 water temperature and Water body salinity variables have been also included (as-is) to complete the Eutrophication and Acidity data. If you use these variables for calculations, please refer to SeaDataNet for having the quality flags: https://www.seadatanet.org/Products/Aggregated-datasets . This aggregated dataset contains all unrestricted EMODnet Chemistry data on Eutrophication and Acidity (14 parameters with quality flag indicators), and covers the North Sea with 587584 CDI records. Data were aggregated and quality controlled by 'Aarhus University, Department of Bioscience, Marine Ecology Roskilde' from Denmark. Regional datasets concerning eutrophication and acidity are automatically harvested and resulting collections are aggregated and quality controlled using ODV Software and following a common methodology for all Sea Regions ( https://doi.org/10.6092/9f75ad8a-ca32-4a72-bf69-167119b2cc12). When not present in original data, Water body nitrate plus nitrite was calculated by summing up the Nitrates and Nitrites. Same procedure was applied for Water body dissolved inorganic nitrogen (DIN) which was calculated by summing up the Nitrates, Nitrites and Ammonium. Quality flags for Water body dissolved inorganic nitrogen (DIN) should be disregarded since that currently they are not based on the original quality flags of nitrite, nitrate and ammonium. Parameter names are based on P35, EMODnet Chemistry aggregated parameter names vocabulary, which is available at: https://www.bodc.ac.uk/resources/vocabularies/vocabulary_search/P35/. Detailed documentation is available at: https://dx.doi.org/10.6092/4e85717a-a2c9-454d-ba0d-30b89f742713 Explore and extract data at: https://emodnet-chemistry.webodv.awi.de/eutrophication>NorthSea The aggregated dataset can be downloaded as ODV collection and spreadsheet, which is composed of metadata header followed by tab separated values. This spreadsheet can be imported to ODV Software for visualisation (More information can be found at: http://www.seadatanet.org/Standards-Software/Software/ODV). The original datasets can be searched and downloaded from EMODnet Chemistry Chemistry CDI Data and Discovery Access Service: https://emodnet-chemistry.maris.nl/search

Water body dissolved inorganic nitrogen (DIN) - Monthly Climatology for the European Seas for the period 1960-2020 on the domain from longitude -45.0 to 70.0 degrees East and latitude 24.0 to 83.0 degrees North. Data Sources: observational data from SeaDataNet/EMODnet Chemistry Data Network. Description of DIVA analysis: The computation was done with the DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.2, using GEBCO 30sec topography for the spatial connectivity of water masses. Horizontal correlation length and vertical correlation length vary spatially depending on the topography and domain. Depth range: 0.0, 5.0, 10.0, 15.0, 20.0, 25.0, 30.0, 35.0, 40.0, 45.0, 50.0, 55.0, 60.0, 65.0, 70.0, 75.0, 80.0, 85.0, 90.0, 95.0, 100.0, 125.0, 150.0, 175.0, 200.0, 225.0, 250.0, 275.0, 300.0, 325.0, 350.0, 375.0, 400.0, 425.0, 450.0, 475.0, 500.0, 550.0, 600.0, 650.0, 700.0, 750.0, 800.0, 850.0, 900.0, 950.0, 1000.0, 1050.0, 1100.0, 1150.0, 1200.0, 1250.0, 1300.0, 1350.0, 1400.0, 1450.0, 1500.0, 1550.0, 1600.0, 1650.0, 1700.0, 1750.0, 1800.0, 1850.0, 1900.0, 1950.0, 2000.0, 2100.0, 2200.0, 2300.0, 2400.0, 2500.0, 2600.0, 2700.0, 2800.0, 2900.0, 3000.0, 3100.0, 3200.0, 3300.0, 3400.0, 3500.0, 3600.0, 3700.0, 3800.0, 3900.0, 4000.0, 4100.0, 4200.0, 4300.0, 4400.0, 4500.0, 4600.0, 4700.0, 4800.0, 4900.0, 5000.0, 5100.0, 5200.0, 5300.0, 5400.0, 5500.0 m. Units: umol/l. The horizontal resolution of the produced DIVAnd analysis is 0.25 degrees.

Moving 6-year analysis of Dissolved Inorganic Nitrogen at Atlantic Sea for each season. - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Every year of the time dimension corresponds to the 6-year centred average of each season. 6-year periods span - from 1988-1993 until 2015-2020 (winter), - from 1988-1993 until 2015-2020 (spring), - from 1986-1991 until 2015-2020 (summer), - from 1984-1989 until 2015-2020 (autumn). Observational data span from 1984 to 2020. Depth range (IODE standard depths): -2000.0, -1750, -1500.0, -1400.0, -1300.0, -1200.0, -1100.0, -1000.0, -900.0, -800.0, -700.0, -600.0, -500.0, -400.0, -300.0, -250.0, -200.0, -150.0, -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -20.0, -10.0, -5.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVA analysis: Geostatistical data analysis by DIVA (Data-Interpolating Variational Analysis) tool. GEBCO 1min topography is used for the contouring preparation. Analyzed filed masked using relative error threshold 0.3 and 0.5 DIVA settings. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Signal to noise ratio was fixed to 1. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. Detrending of data: no, Advection constraint applied: no. Units: umol/l

Seasonal Climatology of Dissolved Inorganic Nitrogen (DIN) for Loire River for the period 1990-2019 and for the following seasons: - winter: January-March, - spring: April-June, - summer: July-September, - autumn: October-December Observational data span from 1990 to 2019. Depth levels (m): -125.0, -100.0, -75.0, -50.0,-40.0, -30.0, -25.0, -20.0, -15.0, -10.0, -8.0, -6.0, -4.0, -2.0, -0.0 Data Sources: observational data from SeaDataNet/EMODNet Chemistry Data Network. Description of DIVAnd analysis: The computation was done with DIVAnd (Data-Interpolating Variational Analysis in n dimensions), version 2.7.4, using GEBCO 30sec topography for the spatial connectivity of water masses. The horizontal resolution of the produced DIVAnd maps grids is 0.01 degrees. Correlation length was optimized and filtered vertically and a seasonally-averaged profile was used. Signal to noise ratio was fixed to 1 for vertical profiles and to 0.1 for time series to account for the redundancy in the time series observations. Logarithmic transformation applied to the data prior to the analysis. Background field: the data mean value is subtracted from the data. . Detrending of data: no, Advection constraint applied: no. Units: umol/l.