EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (48 parameters), and covers the Black Sea with 21504 CDI records divided per matrices: 7 biota profiles, 19677 water profiles, 1820 sediment profiles. Vertical profiles temporal range is from 1974-08-24 to 2017-10-06. Data were aggregated and quality controlled by ‘National Institute for Marine Research and Development "Grigore Antipa"’ from Romania. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names”, but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 48 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

Gridded product for visualization of Water body nitrate plus nitrite in the Black Sea generated by DIVA 4.6.9 using all EMODNET Chemistry data from 1976 to 2013. Depth range (IODE standard depths): 0 – 150m. DIVA settings: signal-to-noise ratio and correlation length were estimated using data mean distance as a minimum (for L), and both parameters vertically filtered. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Every year of the time dimension corresponds to a 10-year centred average for each season: - winter: December - February, - spring: March - May, - summer: June - August, - autumn: September – November Units: umol/l

Gridded product for visualization of Water body dissolved oxygen concentration in the Black Sea generated by DIVA 4.6.11 using all EMODNET Chemistry data from 1970 to 2014. Depth range (IODE standard depths): 0 – 250m. DIVA settings: signal-to-noise ratio and correlation length were estimated using data mean distance as a minimum (for L), and both parameters vertically filtered. Background field: the data mean value is subtracted from the data. Detrending of data: no. Advection constraint applied: no. Every year of the time dimension corresponds to a 10-year centred average for each season: - winter: December - February, - spring: March - May, - summer: June - August, - autumn: September – November Units: umol/l

This visualization product displays beaches locations where non-MSFD monitoring surveys, research & cleaning operations have been applied to collate data on macrolitter (> 2.5 cm). Reference lists associated with these protocols have been indicated with different colors in the map. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processings were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of surveys from non-MSFD monitoring, cleaning and research operations; - Exclusion of beaches without coordinates; - Some categories & some litter types like organic litter, small fragments (paraffin and wax; items > 2.5cm) and pollutants have been removed. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines, the European Threshold Value for Macro Litter on Coastlines and the Joint list of litter categories for marine macro-litter monitoring from JRC (these three documents are attached to this metadata). More information is available in the attached documents. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.

This visualization product displays the cigarette related items abundance of marine macro-litter (> 2.5cm) per beach per year from non-MSFD monitoring surveys, research & cleaning operations without UNEP-MARLIN data. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processings were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of surveys from non-MSFD monitoring, cleaning and research operations; - Exclusion of beaches without coordinates; - Selection of cigarette related items only. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines, the European Threshold Value for Macro Litter on Coastlines and the Joint list of litter categories for marine macro-litter monitoring from JRC (these three documents are attached to this metadata); - Exclusion of surveys without associated length; - Exclusion of surveys referring to the UNEP-MARLIN list: the UNEP-MARLIN protocol differs from the other types of monitoring in that cigarette butts are surveyed in a 10m square. To avoid comparing abundances from very different protocols, the choice has been made to distinguish in two maps the cigarette related items results associated with the UNEP-MARLIN list from the others; - Normalization of survey lengths to 100m & 1 survey / year: in some case, the survey length was not 100m, so in order to be able to compare the abundance of litter from different beaches a normalization is applied using this formula: Number of cigarette related items of the survey (normalized by 100 m) = Number of cigarette related items of the survey x (100 / survey length) Then, this normalized number of cigarette related items is summed to obtain the total normalized number of cigarette related items for each survey. Finally, the median abundance of cigarette related items for each beach and year is calculated from these normalized abundances of cigarette related items per survey. Percentiles 50, 75, 95 & 99 have been calculated taking into account cigarette related items from other sources data (excluding UNEP-MARLIN protocol) for all years. More information is available in the attached documents. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.

This visualization product displays marine macro-litter (> 2.5cm) material categories percentages per beach per year from non-MSFD monitoring surveys, research & cleaning operations. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processings were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of surveys from non-MSFD monitoring, cleaning and research operations; - Exclusion of beaches without coordinates; - Exclusion of surveys without associated length; - Some litter types like organic litter, small fragments (paraffin and wax; items > 2.5cm) and pollutants have been removed. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines, the European Threshold Value for Macro Litter on Coastlines and the Joint list of litter categories for marine macro-litter monitoring from JRC (these three documents are attached to this metadata); - Exclusion of the "feaces" category: it concerns more exactly the items of dog excrements in bags of the OSPAR (item code: 121) and ITA (item code: IT59) reference lists; - Normalization of survey lengths to 100m & 1 survey / year: in some case, the survey length was not 100m, so in order to be able to compare the abundance of litter from different beaches a normalization is applied using this formula: Number of items (normalized by 100 m) = Number of litter per items x (100 / survey length) Then, this normalized number of items is summed to obtain the total normalized number of litter for each survey. To calculate the percentage for each material category, formula applied is: Material (%) = (∑number of items (normalized at 100 m) of each material category)*100 / (∑number of items (normalized at 100 m) of all categories) The material categories differ between reference lists (OSPAR, TSG-ML, UNEP, UNEP-MARLIN, JLIST). In order to apply a common procedure for all the surveys, the material categories have been harmonized. More information is available in the attached documents. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.

This visualization product displays the fishing & aquaculture related plastic items abundance of marine macro-litter (> 2.5cm) per beach per year from non-MSFD monitoring surveys, research & cleaning operations. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processings were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of surveys from non-MSFD monitoring, cleaning and research operations; - Exclusion of beaches without coordinates; - Selection of fishing and aquaculture related plastic items only. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines, the European Threshold Value for Macro Litter on Coastlines and the Joint list of litter categories for marine macro-litter monitoring from JRC (these three documents are attached to this metadata). The selection was adapted to the Joint list of litter categories fishing gears identification and therefore contains some differences with the selection made for previously published versions of this product; - Exclusion of surveys without associated length; - Normalization of survey lengths to 100m & 1 survey / year: in some case, the survey length was not 100m, so in order to be able to compare the abundance of litter from different beaches a normalization is applied using this formula: Number of fishing & aquaculture related plastic items of the survey (normalized by 100 m) = Number of fishing & aquaculture related items of the survey x (100 / survey length) Then, this normalized number of fishing & aquaculture related plastic items is summed to obtain the total normalized number of fishing & aquaculture related plastic items for each survey. Finally, the median abundance of fishing & aquaculture related plastic items for each beach and year is calculated from these normalized abundances of fishing & aquaculture related items per survey. Percentiles 50, 75, 95 & 99 have been calculated taking into account fishing & aquaculture related plastic items from other sources data for all years. More information is available in the attached documents. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.

This visualization product displays the cigarette related items abundance of marine macro-litter (> 2.5cm) per beach per year from non-MSFD monitoring surveys, research & cleaning operations without UNEP-MARLIN data. EMODnet Chemistry included the collection of marine litter in its 3rd phase. Since the beginning of 2018, data of beach litter have been gathered and processed in the EMODnet Chemistry Marine Litter Database (MLDB). The harmonization of all the data has been the most challenging task considering the heterogeneity of the data sources, sampling protocols and reference lists used on a European scale. Preliminary processings were necessary to harmonize all the data: - Exclusion of OSPAR 1000 protocol: in order to follow the approach of OSPAR that it is not including these data anymore in the monitoring; - Selection of surveys from non-MSFD monitoring, cleaning and research operations; - Exclusion of beaches without coordinates; - Selection of plastic bags related items only. The list of selected items is attached to this metadata. This list was created using EU Marine Beach Litter Baselines, the European Threshold Value for Macro Litter on Coastlines and the Joint list of litter categories for marine macro-litter monitoring from JRC (these three documents are attached to this metadata); - Exclusion of surveys without associated length; - Normalization of survey lengths to 100m & 1 survey / year: in some case, the survey length was not 100m, so in order to be able to compare the abundance of litter from different beaches a normalization is applied using this formula: Number of plastic bags related items of the survey (normalized by 100 m) = Number of plastic bags related items of the survey x (100 / survey length) Then, this normalized number of plastic bags related items is summed to obtain the total normalized number of plastic bags related items for each survey. Finally, the median abundance of plastic bags related items for each beach and year is calculated from these normalized abundances of plastic bags related items per survey. Percentiles 50, 75, 95 & 99 have been calculated taking into account plastic bags related items from other sources data for all years. More information is available in the attached documents. Warning: the absence of data on the map does not necessarily mean that they do not exist, but that no information has been entered in the Marine Litter Database for this area.