Mediterranean Sea - Contaminants aggregated datasets 1974/2017 v2018

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (24 parameters), and covers the Mediterranean Sea with 4517 CDI records divided per matrices: 520 biota profiles, 560 water profiles, 3437 sediment (26 Vertical profiles and 3411 Time series). In the water dataset, the vertical profiles temporal range is from 1974-09-12 to 2015-09-14. In sediment dataset, vertical profiles temporal range is from 2010-08-02 to 2014-09-28 and time series temporal range is from 1981-06-27 to 2018-08-02. In biota time series temporal range is from 1979-03-29 to 2017-03-15. Data were aggregated and quality controlled by ‘Hellenic Centre for Marine Research, Hellenic National Oceanographic Data Centre (HCMR/HNODC)’ from Greece. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 24 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

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Arctic Ocean - Contaminants aggregated datasets 1974/2015 v2018

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (20 parameters), and covers the Arctic Ocean with 548 CDI records divided per matrices: 235 water profiles, 313 sediment profiles. Vertical profiles temporal range is from 1974-03-25 to 2015-06-15. Data were aggregated and quality controlled by ‘Institute of Marine Research - Norwegian Marine Data Centre (NMD)’ from Norway. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 20 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

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Baltic Sea - Contaminants aggregated datasets 1972/2017 v2018

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (49 parameters), and covers the Baltic Sea with 3818 CDI records divided per matrices: 1358 biota (396 Vertical profiles and 962 Time series),906 water profiles, 2510 sediment profiles. Vertical profiles temporal range is from 1985-04-16 to 2016-09-27. Time series temporal range is from 1972-05-02 to 2017-10-30. Data were aggregated and quality controlled by ‘Swedish Meteorological and Hydrological Institute (SMHI)’ from Sweden. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 49 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

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Black Sea - Contaminants aggregated datasets 1974/2017 v2018

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (48 parameters), and covers the Black Sea with 21504 CDI records divided per matrices: 7 biota profiles, 19677 water profiles, 1820 sediment profiles. Vertical profiles temporal range is from 1974-08-24 to 2017-10-06. Data were aggregated and quality controlled by ‘National Institute for Marine Research and Development "Grigore Antipa"’ from Romania. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names”, but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 48 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

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North East Atlantic Ocean - Contaminants aggregated datasets 1970/2017 v2018

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (20 parameters), and covers the North East Atlantic Ocean with 2400 CDI records divided per matrices: 122 in biota (as time series), 1689 in water (as vertical profiles), 589 in sediment (478 Vertical profiles and 111 Time series). Vertical profiles temporal range is from 1970-07-29 to 2017-02-28. Time series temporal range is from 1979-02-28 to 2014-10-21. Data were aggregated and quality controlled by ‘IFREMER / IDM / SISMER - Scientific Information Systems for the SEA’ from France. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 20 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

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North Sea - Contaminants aggregated datasets 1970/2017 v2018

EMODnet Chemistry aims to provide access to marine chemistry data sets and derived data products concerning eutrophication, ocean acidification and contaminants. The chemicals chosen reflect importance to the Marine Strategy Framework Directive (MSFD). This regional aggregated dataset contains all unrestricted EMODnet Chemistry data on contaminants (59 parameters), and covers the North Sea with 34978 CDI records divided per matrices: 3909 biota time series, 28071 water profiles, 2998 sediment profiles. Vertical profiles temporal range is from 1970-02-17 to 2017-10-26. Time series temporal range is from 1979-02-26 to 2017-02-28. Data were aggregated and quality controlled by ‘Aarhus University, Department of Bioscience, Marine Ecology Roskilde from Denmark. Regional datasets concerning contaminants are automatically harvested. Parameter names in these datasets are based on P01, BODC Parameter Usage Vocabulary, which is available at: http://seadatanet.maris2.nl/bandit/browse_step.php . Each measurement value has a quality flag indicator. The resulting data collections for each Sea Basin are harmonised, and the collections are quality controlled by EMODnet Chemistry Regional Leaders using ODV Software and following a common methodology for all Sea Regions. Harmonisation means that: (1) unit conversion is carried out to express contaminant concentrations with a limited set of measurement units (according to EU directives 2013/39/UE; Comm. Dec. EU 2017/848) and (2) merging of variables described by different “local names” ,but corresponding exactly to the same concepts in BODC P01 vocabulary. The harmonised dataset can be downloaded as ODV spreadsheet (TXT file), which is composed of metadata header followed by tab separated values. This worksheet can be imported to ODV Software for visualisation (More information can be found at: https://www.seadatanet.org/Software/ODV ). The same dataset is offered also as XLSX file in a long/vertical format, in which each P01 measurement is a record line. Additionally, there are a series of columns that split P01 terms in subcomponents (measure, substance, CAS number, matrix...).This transposed format is more adapted to worksheet applications users (e.g. LibreOffice Calc). The 59 parameter names in this metadata record are based on P02, SeaDataNet Parameter Discovery Vocabulary, which is available at: http://seadatanet.maris2.nl/v_bodc_vocab_v2/vocab_relations.asp?lib=P02 . Detailed documentation will be published soon. The original datasets can be searched and downloaded from EMODnet Chemistry Download Service: https://emodnet-chemistry.maris.nl/search

Hazardous substances in the sediments and their pathways from potential sources in the eastern Gulf of Finland

Contamination by hazardous substances is one of the main environmental problems in the eastern Gulf of Finland, Baltic Sea. A trilateral effort to sample and analyse heavy metals (HMs), polycyclic aromatic hydrocarbons (PAHs), and organotins from bottom sediments in 2019–2020 were conducted along with harvesting historical data in Russian, Estonian and Finnish waters. We suggest that the input of organotins still occurs along the ship traffic routes. The tributyltin content exceeded the established quality criteria up to more than 300 times. High contamination by PAHs found near the ports, most likely originate from incomplete fuel incineration processes. The Neva River Estuary and Luga Bay might potentially suffer from severe cadmium contamination. The high ecological risk attributed to the HMs was detected at deep offshore areas. The simulated accumulation pattern qualitatively agrees with field observations of HMs in sediments, demonstrating the potential of numerical tools to tackle the hazardous substances problems.

Dioxins in the Gulf of Finland sediments (2010-2011)

Dioxins in the Gulf of Finland sediments, impact study during Nord Stream gas pipeline construction, data from 2010-2011

PAHs, PCBs, heavy metals, TOC and grain size in the sediment of Belgian marine harbours.

The chemical status of five dredged spoil disposal sites in the Belgian Part of the North Sea, near the ports of Ostend and Nieuwpoort, is evaluated. A linear mixed-effect model was applied to PCB, PAH and heavy metal data from 2005-2014. No decrease in PCB concentrations was found, with even an increase at two disposal sites. Hg/AL ratios increased with 62% at one disposal site (BR&WS2) from 2005-2006 to 2013-2014. Cu and Zn concentrations increased at two disposal sites. Additional harbour sampling suggests that the latter is possibly linked to antifouling paints. Based on OSPAR environmental assessment criteria, the current chemical status of the sites suggests no chronic effect of dredged spoil disposal. However, increasing time trend data for PCB, Hg, Cu and Zn demonstrate the importance of monitoring to identify adverse trends.

MEPA Inland Water Survey - Pollutants in sediment 2013

The Sediments Baseline Survey was conducted in 10 inland water bodies. The samples were collected between 29th May and 6th June 2013. Two replicate samples of superficial (up to 10 cm depth) sediments were collected from each station using pre-treated samplers. Where water was sufficiently shallow, sediments were collected by hand using a core sampler, while in locations where water bodies were deep, sediment was collected using a hand-held stainless steel grab. The pollutants tested for include the list of priority substances and other pollutants as stipulated in the Environmental Quality Standard Directive (2008/105/EC). Chemical analyses of sediment samples for all parameters analysed were carried out according to standard methodology at CADA Laboratories s.n.c. (Italy), which are accredited according to ACCREDIA 2 CEN/ISO 17025 certification.

Concentration of polychlorobiphenyls (PCBs) in sediment samples